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Lesson 2.6 · AQA Combined Science

Polymers and repeating units

A polymer is a very large molecule

Polymers are very large molecules made from many repeating units. Think of a long chain. Strong covalent bonds join atoms along each chain.

Why polymers are usually solids

Because the molecules are very large, the intermolecular forces between polymer chains are relatively strong compared with those between small molecules. More energy is needed to overcome these forces, so polymers are usually solid at room temperature. Covalent bonds along the chain are also strong.

Read a repeating-unit drawing

The brackets enclose a unit that repeats. The n means a large number of repeats. Bonds pass through the brackets to show the chain continues. This example is poly(ethene); each repeat contains two carbons and four hydrogens.

Keep the two attractions separate

Use covalent bonds within a chain and intermolecular forces between chains. A polymer is not a giant ionic lattice. Most ordinary plastics do not conduct because they lack mobile ions or delocalised electrons.

Remember

Polymers have strong covalent bonds along chains and intermolecular forces between chains. n means many repeats.