01 · Fill from the inside
Electrons occupy shells
Electron configuration shows how electrons are arranged in shells around the nucleus.
In a neutral atom, electrons = atomic number. Fill the innermost shell first.
First shell: up to 2 electrons.
Second shell: up to 8 electrons.
For the first 20 elements: put up to 8 in the third shell, then start the fourth.
Oxygen has 8 electrons: 2 in the first shell and 6 in the second. Write this as 2,6.
02 · Worked example
Sodium: 11 electrons
First shell: 2 electrons. 9 left.Second shell: 8 electrons. 1 left.Third shell: 1 electron.
Sodium’s configuration is 2,8,1. Check: 2 + 8 + 1 = 11.
The outer shell is the occupied shell furthest from the nucleus. Sodium has 1 outer electron.
03 · A fourth shell
Potassium and calcium
For these elements, the fourth shell starts after 2,8,8.
Potassium (19): 2,8,8,1.
Calcium (20): 2,8,8,2.
These are simplified shell diagrams, not to scale. Dots represent electrons.
Remember
Count: electrons = atomic number.
Fill: start with the innermost shell.
Check: add the shell numbers to find the total electrons.